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A member has done this before on his 307, there should be something on here if you do a search.
 

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You would be best repairing the wheels before painting them or they'll still look a mees - just a different colour mess. You can get alloy wheel repair kits from ebay which contain a filler, paint and laquer. I think they also contain different grades of wet & dry as well.

You probably would do a better job if the wheels were off the car as it will be easier to see any blemishes before you start spraying. No need to remove the tyres as they can be masked easily.

Problem with repairing them, especially if you paint them a different colour is it will be very visible if you kerb one again.
 

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If you want a good job, you're best avoiding aerosols and using a compressor and spray gun, as well as a bit of know how on achieving a good result.

You'll need to give them a really good clean an degrease them.

Give them a good rub with P400 paper (good quality stuff), and prime any bare metal with an etch primer.

You'll need a good filler - "metalik" is a good choice.

A few light coats of primer is essential, with a light rub in between coats. Allow to dry properly.

Then apply a few light coats of colour, avoiding runs and temptation to do a quick job.

Lacquer up, a few light coats is best.

The most important thing is patience. Don't be tempted to cake it on. It's also best to work through the grades of paper, and skills like flattening off give a better finish.
 
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